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Publications in 1983


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The numbers following each publication are linked to the structures reported in the publication.

1983
  1. Chisholm, M. H.; Folting, K.; Hoffman, D. M.; Huffman, J. C.; Leonelli, J.: The Remarkable Role of Steric Factors in the Reactions of Alkynes (HCCH and MeCCMe) with Ditungsten Hexaalkoxides: Crystal and Molecular Structure of W2(OiPr)6(py)2(.mu.C2H2), W2(OCH2But)6(py)2(.mu.C2Me2)and W2(OPri)6(.mu.C4R4)(C2R2) where R=H and Me. J. Chem. Soc., Chem. Commun. 1983, 58991.
    82101, 82009, 82089, 82088
  2. Curtis, T. L.; Huffman J. C.: An Interactive Program for the Interpretation of Patterson Functions and Its Uses. Proc. Indiana Acad. Sci. 1983, 92, 15357
  3. Chisholm, M. H.; Huffman, J. C.; Ratermann, A. L.: Reactions of MetalMetal Multiple Bonds. 9. .alpha.Diketone Adducts of Ditungsten Hexaalkoxides: W2(OR)6(O2C2R'2)2(MM). Inorg. Chem. 1983, 22, 41005.
    82071
  4. Wiggins, R. W.; Huffman, J. C.; Christou, G.: Vanadium Thiolate Chemistry: Preparation and Structures of [NMe4]Na[VO(SCH2CH2S)2].2EtOH and [Ph4P]2[V2(SCH2CH2S)4]. J. Chem. Soc., Chem. Commun. 1983, 131315.
    83073, 83056
  5. Christou, G.; Huffman, J. C.: Preparation and Structural Characterization of [NET4]2[Mn2(SCH2CH2S)4], a Stable Manganese(III)thiolate Dimer. J. Chem. Soc., Chem. Commun. 1983, 55860.
    82091
  6. Noble, M. E.; Folting, K.; Huffman, J. C.; Wentworth R. A. D.: Partial Hydrolysis of [Mo(NR)(.mu.3S)(S2P(OR')2]4 and Molecular Structures of Mo2O(NC6H4CH3)(.mu.S)2(S2P(OCH3)2)2 and Cubanelike [Mo2O(NC6H5)(.mu.3S)2(S2P(OC2H5)2)2)]2. Inorg. Chem. 1983, 22, 36713676.
    82069, 83501
  7. Siddall, T. L.; Miyaura, N.; Huffman, J. C.; Kochi, J. K.: Isolation and Molecular Structure of Unusual Oxochromium(V) Cations for the Catalytic Epoxidation of Alkenes. J. Chem. Soc., Chem. Commun. 1983, 118586.
    83055
  8. Nieman, J.; Teuben, J. H.; Huffman, J. C.; Caulton, K. G.: Preparation and Characterization of MonoCyclopentadienylvanadium Dihalide BisPhosphine Complexes; Crystal Structure of (.eta.5 C5H5)VCl2(PMe3)2. J. Organomet. Chem. 1983, 255, 193204.
    82044
  9. Luetkens, M. L., Jr.; Elcesser, W. L.; Huffman, J. C.; Sattelberger, A. P.: Isolable Paramagnetic Hydride Complexes of Niobium(IV) and Tantalum(IV). J. Chem. Soc., Chem. Commun. 1983, 107274.
    83913
  10. Coffindaffer, T. W.; Rothwell, I. P.; Huffman, J. C.: Dinuclear Aryloxide Chemistry. 1. A Direct Comparison of Aryloxide and Alkoxide Coordination to a Dimetal Center. Synthesis and Structure of 1,2Bis(isopropoxy)tetrakis(2,6dimethylphenoxy)dimolybdenum (Mo.tplbnd.Mo). Inorg. Chem. 1983, 22, 290610.
    82916
  11. Chisholm M. H.; Hoffman, D. M.; Huffman, J. C.: Isoelectronic Molecules with Triple Bonds to Metal Atoms (M = Mo, W): Molecular Structures of Tritertbutoxytungsten Ethylidyne and Nitride. Inorg. Chem. 1983, 22, 290306.
    82087, 82083
  12. Bansemer, R. L.; Huffman J. C.; Caulton, K. G.: A Bimetallic Vanadium(I) Polyhydride. J. Am. Chem. Soc. 1983, 105, 616364.
    83051
  13. Chisholm, M. H.; Huffman, J. C.; Marchant, N. S.: Reactions of MM Triple Bonds with CN Triple Bonds: Adduct Formation (M=Mo) and Metathesis (M=W) As Seen in the Reactions between Dimethylcyanamide and Hexaalkoxides of Dimolybdenum and Ditungsten. J. Am. Chem. Soc. 1983, 105, 616263.
    83041, 83028
  14. Coffindaffer, T. W.; Rothwell, I. P.; Huffman, J. C.: Conversion of L3Mo.trplbnd.MoL3 to L3Mo(.mu.L)3MoL3 Type Compounds and Mechanistic Implications. Inorg. Chem. 1983, 22, 317879.
    83902
  15. Coffindaffer, T. P.; Rothwell, I. P.; Huffman, J. C.: Synthesis and Structure of a Dimolybdenum AlkylidyneHydride. J. Chem. Soc., Chem. Commun. 1983, 124951.
    83911, 83047
  16. Chisholm, M. H.; Hoffman, D. M.; Huffman, J. C.: Coupling C.tplbnd.C, C.tplbnd.N, and W.tplbnd.W Bonds. Preparation, and Crystal and Molecular Structure of Hexaneopentoxy(pyridine)[2amino(2) W1,W15amido(2)W23,4dimethylhexa2,4diene]ditungsten W2(OCH2But)6(py)(N[CMe]4N). J. Chem. Soc., Chem. Commun. 1983, 96768.
    83009
  17. Chisholm, M. H.; Corning, J. F.; Huffman, J. C.: Mo2(SC6H2Me3)6. The First Example of a Compound Containing a MoMo Triple Bond Supported by Six Mercaptido Ligands. J. Am. Chem. Soc. 1983, 105 592425.
    83046
  18. Chetcuti, M. J.; Chisholm, M. H.; Chiu, H. T.; Huffman, J. C.: Incorporating MetalMetal Multiple Bonds into Heterometallic Chains: Bis(tris(trimethylstannyl)tin)tetrakis(dimethylamido)dimolybdenum and ditungsten and Related Compounds. J. Am. Chem. Soc. 1983, 105, 10601.
    82068
  19. Grieco, P. A.; Yoshida, K.; Huffman, J. C.: Aqueous Intermolecular DielsAlder Chemistry: Novel Products Derived from Substituted Benzoquinonediene Carboxylate Adducts via Tandem Michael Reactions. Tetrahedron Lett. 1983, 24, 380710.
    82096
  20. Santure, D. J.; Huffman, J. C.; Sattelberger, A. P.: MetalMetalBonded Complexes of the Early Transition Metals. 7. The Ditungsten Tetracarboxylate Story. Inorg. Chem. 1983, 22, 187783.
    82906, 8046
  21. Wall, K. L.; Folting, K.; Huffman, J. C.; Wentworth, R. A. D.: Isolation and Molecular Structures of Dinuclear [Mo(NC6H4CH3)(.mu. S)(S2CN(iC4H9)]2 and Cubanelike [Mo(NC6H4CH3)(.mu.3S)(S2CN(iso C4H9)2]4, two Oligomers in Equilibrium. Inorg. Chem. 1983, 22, 236671.
    82021, 82020
  22. Luetkens, M. L. Huffman, J. C.; Sattelberger, A. P.: Development of Lowvalent Tantalum Chemistry: Syntheses and Xray Structures of [TaCl2(PMe3)4], [TaCl2H2(PMe3)4] and [TaClH2(PMe3)4]. J. Am. Chem. Soc. 1983, 105, 44745.
    82933, 82934, 82910
  23. Shiu, K. B.; Curtis, M. D.; Huffman, J. C.: Metalmetal Multiple Bonds. 15. Syntheses and Structures of the 17 electron Radical TpMo(CO)3 and the Triply Bonded Dimer Tp2Mo2(CO)4 (Mo.tplbond.Mo) (Tp=hydridotris(pyrazolyl)borate). Organometallics. 1983, 2, 9368.
    82935
  24. Gallagher, T., Magnus, P.; Huffman, J. C.: Pentacyclic Systems of Indole Alkaloids. Formation of the C11C12 Bond. Two Syntheses of (+)Aspidospermidine. J. Am. Chem. Soc. 1983, 105, 47507.
    81064
  25. Rhodes, L. F.; Huffman, J. C.; Caulton, K. G.: An Unprecedented Ligand Set and Coordination Geometry for Copper(I). J. Am. Chem. Soc. 1983, 105, 51378.
    82064, 82076
  26. Noble, M. E.; Huffman, J. C.; Wentworth, R. A. D.: Addition of Carboxylic Acids to [Mo(NC6H4CH3)(.mu3.S)(S2P(OC2H5)2)]4 and the Molecular Structure of [Mo(NC6H4CH3)(S2P(OC2H5)2)]2(.mu. S)(.mu.SH)(.mu.O2CCF3). Inorg. Chem. 1983, 22, 175660.
    82006
  27. Haymore, B. L.; Huffman, J. C.; Butler, N. E.: Linear vs. Bent Nitrosyl Ligands in Pseudotetrahedral Nitrosyl Complexes. LowTemperature Structure of CoI(NO)2(P(C6H5)3). Inorg. Chem. 1983, 22, 16870.
    7607
  28. Chisholm, M H.; Huffman, J. C.; Tatz, R. J.: .beta.Hydrogen Effects in Alkylalkoxides of Dimolybdenum (M.tplbnd.M). J. Am. Chem. Soc. 1983, 105,20757
    81034
  29. Chetcuti, M. J.; Chisholm, M. H.; Folting, K.; Haitko, D. A.; Huffman, J. C.; Janos, J.: 1,2Dibenzyl and 1,2Diaryltetrakis(dimethyl-amido)dimolybdenum and ditungsten Compounds: M2R2(NMe2)4 (M.tplbnd.M). Structural Effects of Me2NtoM .pi. Bonding. J. Am. Chem. Soc. 1983, 105, 116370.
    81076, 81074, 81057
  30. Chetcuti, M. J.; Chisholm, M. H.; Huffman, J. C.; Leonelli, J.: Oxidative Additions to (W.tplbnd.W)6+ Centers: The Influence of Lewis Base Association Reactions. J. Am. Chem. Soc. 1983, 105, 2923.
    82041
  31. Chisholm, M. H.; Huffman, J. C.; Kirkpatrick, C. C.: Reactions of Mo2(OR)6 (M.tplbnd.M) Compounds (R = iPr and tBu) with Benzoyl Peroxide. Inorg. Chem. 1983, 22, 17047.
    8058
  32. Chisholm, M. H.; Corning, J. F.; Huffman, J. C.: The MolybdenumMolybdenum Triple Bond. 12. Preparation and Characterization of Bis(tertbutylmercaptido)tetrakis(dimethylamido)dimolybdenum (M.tplbnd.M). Inorg. Chem. 1983, 22, 3840.
    81045
  33. Geerts, R. L.; Huffman, J. C.; Folting, K.; Lemmen, T. H.; Caulton, K. G.: Concerning the Structure and Stability of a Copper(I) Alkoxy Carbonyl. J. Am. Chem. Soc. 1983, 105, 35036.
    82073
  34. Green, M. A.; Huffman, J. C.; Caulton, K. G.: Photochemistry of Transitionmetal Polyhydrides: Dimerization of OsH4(PMe2Ph)3 Following Photodissociation of Dihydrogen. J. Organomet. Chem. 1983, 243, C78C82.
    82005, 82004

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