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Publications in 1986


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The numbers following each publication are linked to the structures reported in the publication.

1986
  1. Horn, S. P.; Folting, K.; Huffman, J. C.: The Crystal and Molecular Structure of Oxysanguinarine Obtained from Sanguinaria canadensis L., Papaveraceae. Proc. Indiana Acad. Sci. 1986, 95, 17781.
    84200
  2. Wang, R.; Folting, K.; Huffman, J. C.; Chamberlain, L. R.; Rothwell, I. P.: Synthesis and Solid State Structure of Tetra(2,6,diisopropylphenoxy)hexamethoxyditantalum(V), Ta2(OC6H3Priso2)4(OCH3)6. Inorg. Chim. Acta, 1986, 120, 813.
    84934
  3. Williams, D. R.; Phillips, J. G.; White, F. H.; Huffman, J. C.: Studies of Stereochemical Control Using .alpha.Lithiosulfinyl Carbanions. Tetrahedron, 1986, 42, 300-311.
    8041
  4. Chamberlain, L. R.; Rothwell, I. P.; Huffman, J. C.: Reactivity of Tantalum .eta.2Iminoacyl Groups: Intramolecular Coupling, Reduction, and Dealkyation. J. Chem. Soc., Chem. Commun. 1986, 12035.
    85906
  5. Chisholm, M. H.; Huffman, J. C.; Marchant, N. S.: Carbonylation of (ButO)3W.tplbnd.CNMe2 and (PriO)3(py)2W.tplbnd.CNMe2 (py = pyridine): Two Different Modes of CarbonCarbon Bond Formation. J. Chem. Soc., Chem. Commun. 1986, 71-78.
    85153
  6. Pavacik, P. S.; Huffman, J. C.; Christou, G. C.: A Manganese(IV) Complex with Phenoxide and Carboxylatelike Ligation: Preparation and Structure of [Mn(sal)2(bipyl)] (H2sal = Salicylic Acid: bipy = 2,2'Bipyridine). J. Chem. Soc., Chem. Commun. 1986, 43-44.
    85065
  7. Chisholm, M. H.; Huffman, J. C.; van der Sluys, W.: Synthesis and Characterization of bis(neopentyl)tetrakis(acetato)dimolybdenum. A Notahttp://bly Short Metal Metal distance for a d3d3 Dinuclear Compound Containing a MM Triple Bond of Valence Molecular Orbital Configuration .pi.4.delta.2. Inorg. Chim. Acta. 1986, 116, L13-L14.
    85132
  8. Chisholm, M. H.; Clark, D. L.; Folting, K. F.; Huffman, J. C.: The First Observation of the Equilibrium 2M.tplbnd.M .dbarrow. M4 (M = Transition Metal): Synthesis and Structure of Hexaisopropoxyditungsten and its Dimer. Angew. Chem. Intl. Ed. Engl. 1986, 25, 101421.
    86060
  9. Chisholm, M. H.; Conroy, B. K.; Huffman, J. C.; Marchant, N. S.: Evidence for Equilibria between .mu.Alkyne and Alkylidyne Complexes of Tungsten Alkoxides: [W2(OR)6(.mu.C2R'2)].dbarrow.2[(RO)3W.tplbnd.CR']. Angew. Chem. Intl. Ed. Engl. 1986, 25, 4468.
    85144
  10. Lemmen, T. H.; Huffman, J. C.; Caulton, K. G.: Synthesis of [Cu3Os3H9(PMe2Ph)9], a Bimetallic Raft, by Reductive Elimination of Alcohol or H2. Angew. Chem. Intl. Ed. Engl. 1986, 25, 2624.
    85135
  11. Chisholm, M. H.; Chiu, H. T.; Huffman, J. C.: Unexpected Products Formed by the Addition of Halogens [X2 (= I2 or Br2)] to W2(O2CBut)4(M.tplbnd.M): the Xray Crystal Structures of [W2(O2CBut)5.2ButCONMe2]+[W2I4(O2CBut)2] and W2Br2(O2CBut)3.2THF. Polyhedron. 1986, 5, 137780.
    84028
  12. Beshouri, S. M.; Rothwell, I. P.; Folting, K.; Huffman, J. C.; Streib, W. E.: Synthesis and Structure of Hexabenzyldimolybdenum (Mo.tplbnd.Mo). Polyhedron. 1986, 5, 11915.
    85911
  13. Chou, C. Y.; Devore, D. D.; Huckett, S. C.; Maata, E. A.; Huffman, J. C.; Takusagawa, F.: Organoimido Complexes of Mo(IV), Mo(V), and Mo(VI): Preparation, Structure and Reactivity. Polyhedron. 1986, 5, 3014.
    86501
  14. Caulton, K. G.; Goeden, G. V.; Lemmen, T. H.; Rhodes, L. F.; Huffman, J. C.: Rational Syntheses of Copper Polyhydride Complexes. Biological & Inorganic Copper Chemistry; Volume I., edited by Solomon, E. I., Adenine Press, P.O. Box 355, Guilderland, NY. 1986.
  15. Wilmoth, M. A.; Bernhardt, R. J.; Eyman, D. P.; Huffman, J. C.: Carbonylation of (.eta.6C6(CH3)6)Mn(CO)2H. Organometallics. 1986, 5, 255960.
    84910
  16. Chisholm, M. H.; Conroy, B. K.; Folting, K.; Hoffman, D. M.; Huffman, J. C.: Alkyne Adducts of Ditungsten Hexaneopentoxide and AlkylidyneCapped Tritungsten Compounds Supported by Neopentoxide Ligands. Organometallics. 1986, 5, 245764.
    84029, 84040
  17. Chisholm, M. H.; Conroy, B. K.; Huffman, J. C.: Competitive CarbonCarbon Bond Formation and Cleavage and Cluster Formation in the Reaction between 3Hexyne and Hexaisopropoxyditungsten. Organometallics. 1986, 5, 23845.
    86018
  18. Ahmed, K. J.; Chisholm, M. H.; Folting, K.; Huffman, J. C.: Alkyne Adducts of Mixed ChloroDimethylamido Ditungsten Compounds. Organometallics. 1986, 5, 217180.
    85032, 85005, 84091
  19. Chisholm, M. H.; Eichorn, B. W.; Folting, K. F.; Huffman, J. C.; Tatz, R. J.: Metal AlkoxidesModels for Metal Oxides. 11. Synthesis and Properties of Mixed Alkyl/Aryl/Benyzl Alkoxides of Formula 1,2W2R2(OR')4 and W2R(OR')5 (M.tplbnd.M). Organometallics. 1986, 5, 1599-1606.
    85101, 83017
  20. Shapley, P. A. (Belmonte); Own, Z.Y.; Huffman, J. C.: Alkylation of Osmium(VI) Nitrido Complexes: Reaction of [Os(N)R4][NnBu4] with [Me3O][BF4] and the Xray Crystal Structures of [Os(N)(CH2SiMe3)4][NnBu4] and [Os(NMe)(CH2SiMe3)4]. Organometallics. 1986, 5, 126971.
    84930, 84929
  21. Bernhardt, R. J.; Wilmoth, M. A.; Weers, J. J.; LaBrush, D. M.; Eyman, D. P.; Huffman, J. C.: Derivatives of the (Arene)M(CO)2 (M = Mn or Re) Fragment. The Molecular Structure of (.eta.6C6Me6)Mn(CO)2Cl. Organometallics. 1986, 5, 8838.
    84902
  22. Chisholm, M. H.; Folting, K.; Huffman, J. C.; Marchant, N. S.: An Unexpected CarbonCarbon Bond Formation in the Reaction between Mo2(ONp)6(.mu.NCNEt2) and MeC.tplbnd.CMe. Organometallics. 1986, 5, 6023.
    84064, 85069
  23. Lundquist, E. G.; Huffman, J. C.; Caulton, K. G.: Formation of a Heterometallic Carbon Dioxide Complex with Concurrent Reduction of CO2. J. Am. Chem. Soc. 1986, 108, 830910.
    86080
  24. Chisholm, M. H.; Hammond, C. E.; Ho, D.; Huffman, J. C.: CarbonNitrogen Bond Formation in the Reaction between Tetrakis(dimethylamido)-molybdenum(IV) and 2,6Dimethylphenyl Isocyanide. Preparation and Characterization of the First Homoleptic Metallaamidine Complex: Mo(.eta.2Me2NCN2,6Me2C6H3)4. J. Am. Chem. Soc. 1986, 108, 786061.
    86025
  25. Buchwald, S. L.; Watson, B. T.; Huffman, J. C.: The Trimethylphosphine Adduct of the ZirconoceneBenzyne Complex: Synthesis, Reactions, and Xray Crystal Structure. J. Am. Chem. Soc. 1986, 108, 74112.
    86805
  26. Montgomery, L, K.; Huffman, J. C.; Jurczak, E. A.; Grendze, M. P.: The Molecular Structures of Thiele's and Chichibabin's Hydrocarbons. J. Am. Chem. Soc. 1986, 108, 600411.
    84403, 83204, 84404, 84405
  27. Bashkin, J. S.; Huffman, J. C.; and Christou, G.: Synthetic Model Approach to the Manganese(III) Acid Phosphatase and Its Iron(III)Substituted Form. J. Am. Chem. Soc. 1986, 108, 50389
    85509,86001
  28. Curtis, M. D.; Shiu, K.B.; Butler, W. M.; Huffman, J. C.: Synthesis, Structures and Molecular Orbital Analysis of Hydridotris(pyrazolyl)borate (Tp) Molybdenum Carbonyls: Paramagnetic TpMo(CO)3 and Triply Bonded Tp2Mo2(CO)4 (Mo.tplbnd.Mo). J. Am. Chem. Soc. 1986, 108, 333543.
    82935
  29. Chamerlain, L. R.; Rothwell, I. P.; Huffman, J. C.: Intramolecular Activation of Aliphatic CarbonHydrogen Bonds at Tantalum(V) Metal Centers: A comparixon of Activation by Methyl and Methylidene Functional Groups. J. Am. Chem. Soc. 1986, 108, 15028.
    82903, 84936
  30. Ahmed, K. J.; Chisholm, M. H.; Folting, K.; Huffman, J. C.: Study of the Formation of a .sigma.,.pi.Vinyl Ligand by Hydrogen Atom Transfer from a Coordinated Dimethylamide to a Perpendicularly Bonded Ethyne Ligand. Preparation and Characterization of (PMe2Ph)Cl2W(.mu. .eta.1,.eta.2CHCH2)(mu. .eta.2,.eta1CH2NMe)WCl(NMe2)(PMe2Ph). J. Am. Chem. Soc. 1986, 108, 989999.
    84086, 84073
  31. Chisholm, M. H.; Huffman, J. C.; Smith, C. A.: Metal AlkoxidesModels for Metal Oxides. 9. Hydridoditungsten Alkoxides: W2(H)(OiPr)8Na.diglyme and W2(H)(I)(OCH2tBu)6(H2NMe). Further Investigations of the Reaction between W2(NMe2)6(M.tplbnd.M) and iPrOH Leading to W4(H)2(OiPr)14. J. Am. Chem. Soc. 1986, 108, 22230.
    84028, 84077
  32. Todd, L. J.; Arafat, A.; Baier, J.; Huffman, J. C.,: Recent Studies of Thia and Azaboranes. VCH Puhttp://blishers, Inc. Deerfield Beach, Flordia, 334421705. R. E. Williams and J. F. Liebman, Eds. 1986.
  33. Money J. K.; Folting, K.; Huffman, J. C.; Collison, D.; Temperley, J.; Mabbs, F. E.; Christou, G. C.: Isolation and Structure of [V(OSiMe3)(edt)2] (edt2 = Ethane1,2 dithiolate), an Intermediate in the Conversion of [VO(edt)2]2 to [VS(edt)2]2 with (Me3Si)2S. EPR Characterization of the Series [VE(LL)2]2 (E = O, S, OSiMe3, LL = edt; E = O, LL = pdt). Inorg. Chem. 1986, 25, 45838.
    84105
  34. Chan, D. M.T.; Chisholm, M. H.; Folting, K.; Huffman, J. C.; Marchant, N. S.: Trialkoxynitridomolybdenum Compounds: (RO)3Mo.tplbnd.N. Preparation, Structures (R = tBu and iPr), and Comparisons with a Tungsten Analogue (R = tBu). Inorg. Chem. 1986, 25, 41704.
    85051, 85207, 85007
  35. Money, J. K.; Nicholson, J. R.; Huffman, J. C.; Christou, G.: Discrete MetalSulfideThiolate Complexes of an Early 3d Transition Metal. Inorg. Chem. 1986, 25, 40723.
    86046, 85160
  36. Arafat, A.; Baer, J.; Huffman, J. C.; Todd, L. J.: Chemical and Structural Studies of Azaboranes. Inorg. Chem. 1986, 25, 375760.
    83229
  37. Goeden, G. V.; Huffman, J. C.; Caulton, K. G.: A Cu(.mu.H) Bond Can Be Stronger Than an Intramolecular P>Cu Bond. Synthesis and Structure of Cu2(.mu.H)2[.eta.2CH3C(CH2PPh2)3]2. Inorg. Chem. 1986, 25, 24845.
    81072
  38. Geerts, R. L.; Huffman, J. C.; Caulton, K. G.: Soluhttp://ble Zinc Bis(aryloxides). Inorg. Chem. 1986, 25, 18035.
    83116
  39. Chisholm, M. H.; Chiu, H. T.; Huffman, J. C.; Wang, R. J.: The TungstenTungsten Triple Bond. 12. Bis(1,3 diaryltriazenido)bis(dimethylamido)diethylditungsten(M.tplbnd.M) Compounds. Inorg. Chem. 1986, 25, 10926.
    84080, 84103
  40. Vincent, J. B.; Folting, K.; Huffman, J. C.; Chrisou, G.: Use of Tetranbutylammonium Permanganate for Inorganic Synthesis in Nonaqueous Solvents. Preparation and Structure of a Manganese(III) Dimer Containing Bridging Phenoxo Oxygen Atoms. Inorg. Chem. 1986, 25, 9969.
    85037
  41. Chou, C. Y.; Huffman, J. C.; Maatta, E. A.: Preparation and Reactivity of Monomeric (Tolylimido)molybdenum(V) Complexes and the Structure of merTrichlorotrans bis(ethyldiphenylphosphine)(ptolylimido)molybdenum(V), Mo(Ntol)Cl3(EtPh2P)2. Inorg. Chem. 1986, 25, 8226.
    84912
  42. Geerts, R. L.; Huffman, J. C.; Caulton, K. G.: Relationship of Adduct Formation to Bimolecular Reductive Elimination from Rhodium Polyhydrides. Inorg. Chem. 1986, 25, 5901.
    85112

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