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The numbers following each publication are linked to the structures reported in the publication.

1990
  1. Lundquist, E. G.; Folting, K.; Streib, W. E.; Huffman, J. C.; Eisenstein, O.; Caulton, K. G.: Reactivity of the Molecular Hydrogen Complex [IrH4(PMe2Ph)3]BF4 toward Olefins. The Origin of Stereochemical Rigidity of M(PR3)3(olefin)2 Species.  J. Am. Chem. Soc. 1990, 112, 855-864.
    87210, 88100
  2. Astley, S. T.; Takats, J.; Huffman, J. C.; Streib, W. E.: Solid-State Structure and Fluxional Solution Behavior of the Ambident Organometallic Nucleophiles (eta3-C7H7)M(CO)3-(M = Ru, Os).  Organometallics. 1990, 9, 184-189.
    88807, 88808
  3. Lundquist, E. G.; Huffman, J. C.; Folting, K.; Mann, B. E.; Caulton, K. G.: Synthesis and Reactivity of a Heterometallic CO2 Complex.  Inorg. Chem. 1990, 29, 128-134.
    86080, 87110
  4. Hneihen, A. S.; Bruno J. W.; Huffman, J. C.: Regiochemical and mechanistic studies of the addition of tin hydride and oxide to substituted ketenes. J. Organomet. Chem. 1990, 382, 361-375.
    87851
  5. Lei, D.; Hampden-Smith, M. J.; Duesler, E. N.; Huffman, J. C.: Synthesis and Single-Crystal X-ray Structural Investigation of 1,1-Bis(pentacarbonylmanganio)-3,4-dimethylgermacyclopent-3-ene and Bis[1-tetracarbonylferrio)-3,4-dimethylgermacyclopent-3-ene]: The First Evidence for a Puckered Ground-State Conformation in Germacyclopent-3-enes.  Inorg. Chem. 1990, 29, 795-798. 
    88924
  6. Williams, R. A.; Hanusa, T. P.; Huffman, J. C.: Synthesis and Crystallographic Characterization of (Me5C5)2Ca(Me3SiC = C-C=CSiMe3): The First Monomeric Diyne Complex of a Main-Group Element. J. Am. Chem. Soc. 1990, 2454-2455.
    89912
  7. Magnus, P.; Danikiewicz, W.; Katoh, T.; Huffman, J. C.; Folting K.: Synthesis of Helical Poly-?-pyrroles. Multiple Atropisomerism Resulting in Helical Enantiomorphic Conformations.  J. Am. Chem. Soc. 1990, 112, 2464-2465. 
    88158
  8. Burns, C. J.; Smith, W. H.; Huffman, J. C.; Sattelberger, A. P.: Uranium(VI) Organoimido Complexes.  J. Am. Chem. Soc. 1990, 112, 3237-3239. 
    88912, 89908
  9. Williams, R. A.; Hanusa, T. P.; Huffman, J. C.: Structures of Ionic Decamethylmetallocenes: Crystallographic Characterization of (Me5C5)2Ca and (Me5C5)2Ba and a Comparison with Related Organolanthanide Species.  Organometallics. 1990, 9, 1128-1134.
    89907, 87837
  10. Tesh, K. F.; Hanusa, T. P.; Huffman, J. C.: Ion Pairing in [Bis(trimethylsilyl)amido]potassium: X-ray Crystal Structure of Unsolvated [KN(SiMe3)2]2.  Inorg. Chem. 1990, 29, 1584-1586.
    89904
  11. Lis, R.; Traina, J. A.; Huffman, J. C.: A Novel Synthetic Route to 1,2-Dimethyl-5-phenyl-lH-imidazo[4,5-b]pyridin-7-ol.  J. Heterocycl. Chem. 1990, 27, 531-534.
    88955
  12. Christou G.; Perlepes, S. P.; Folting, K.; Huffman, J. C.; Webb, R. J.; Hendrickson, D. N.: A New Class of Bipyridine-ligated Metal Carboxylate Complexes: Characterization of the Triply-bridged Ferromagnetically-coupled Complexes [Cu2(OAc)3)(bpy)2](ClO4) and [Cu2(OH)(H2O)(OAc)(bpy)2](ClO4)2].  J. Chem. Soc., Chem. Commun. 1990, 10, 746-747.
    88087, 88124
  13. Van Der Sluys, L. S.; Eckert, J.; Eisenstein, O.; Hall, J. H.; Huffman, J. C.; Jackson, S. A.; Koetzle, T. F.; Kubas, G. J.; Vergamini, P. J.; Caulton, K. G.: An Attractive "Cis-Effect" of Hydride on Neighbor Ligands: Experimental and Theoretical Studies on the Structure and Intramolecular Rearrangements of Fe(H)2(.eta.2-H2)(PEtPh2)3.  J. Am. Chem. Soc. 1990, 112, 4831-4841.
    86168, 86008
  14. Chestnut, R. W.; Yu, J. S.; Fanwick, P. E.; Rothwell, I. P.; Huffman, J. C.: The Cyclometallation of 2,6-Diphenylphenoxide (OAr-2,6Ph2) Ligands at Niobium(V) and Tantalum(V) Metal Centres: The Solid State Structures of the Monocyclometallated Compounds Ta(OC6H3Ph-C6H4)(OAr-2,6Ph2)2(R)(R=CH3, n-C4H9) and Nb(OC6H3Ph-C6H4)(OAr-2,6Ph2)2(Cl).  Polyhedron. 1990, 9, 1051-1059.
    87910
  15. Libby, E.; Folting, K.; Huffman, J. C.; Christou, G.: Feasibility of a "Building Block" Approach to Higher Nuclearity Mn/O/RCO2- Aggregates: Directed Conversion of a [Mn4O2] to an [Mn8O4] Complex.  J. Am. Chem. Soc. 1990, 112, 5354-5356.
    89182
  16. Chisholm, M. H.; Huffman, J. C.; Klang J. A.: A Convenient Synthesis of Trialkylalkylidyne Tungsten (6+) Compounds and the X-Ray Crystal Structure of (Me3CCH2)3W=CPh(py).  Polyhedron. 1990, 9, 1271-1276.
    87227
  17. Chisholm, M. H.; Parkin, I. P.; Huffman, J. C.; Streib, W. E.: Triple Bonds between Molybdenum and Tungsten Atoms supported by Selenolate Ligands: M2(SeAr)6 and M2(OPri)2(SAr)4(Ar = Mesityl).  J. Chem. Soc., Chem. Commun. 1990, 13, 920-921. 
    89231, 89240, 89270, 89234
  18. Ligand. Siedle, A. R.; Huffman, J. C.: Organometallic Chemistry of Fluorocarbon Acids, Structure of Ti2(i-PrO)4(?-i-PrO)2[HC(SO2CF3)2-O,O]2, an Example of an Oxygen-Bonded HC(SO2CF3)2  Inorg. Chem. 1990, 29, 3131-3134.
    87810
  19. Vaartstra, B. A.; Huffman, J. C.; Gradeff, P. S.; Hubert-Pfalzgraf, L. G.; Daran, JC; Parraud, S; Yunlu, K.; Caulton, K. G.: Alcohol Adducts of Alkoxides: Intramolecular Hydrogen Bonding as a General Structural Feature.  Inorg. Chem. 1990, 29, 3126-3131.
    89136, 89157
  20. Lundquist, E. G.; Folting, K.; Huffman, J. C.; Caulton K. G.: Generation and Reactivity of Unsaturated Iridium and Rhodium Dimethyl Complexes.  Organometallics. 1990, 9, 2254-2261.
    88018, 87211
  21. Beshouri, S. M.; Chebi, D. E.; Fanwick, P. E.; Rothwell, I. P.; Huffman, J. C.: Synthetic and Mechanistic Investigation of the Rearrangement of eta2-Iminoacyl Ligands of Group 4 Metals to Vinylamido Groups via a Facile 1,2-Hydrogen Shift.  Organometallics. 1990, 9, 2375-2386. 
    86917
  22. Christou, G.; Perlepes, S. P.; Libby, E.; Folting, K.; Huffman, J. C.; Webb, R. J.; Hendrickson, D. N.: Preparation and Properties of the Triply Bridged, Ferromagnetically Coupled Dinuclear Copper(II) Complexes [Cu2(OAc)3(bpy)2](ClO4) and [Cu2(OH)(H2O)(OAc)(bpy)2](ClO4)2.  Inorg. Chem. 1990, 29, 3657-3666.
    88087, 88124
  23. Lemmen, T. H. ; Goeden, G. V.; Huffman, J. C.; Geerts, R. L.; Caulton, K. G.: Alcohol Elimination Chemistry of (CuOtBu)4.  Inorg. Chem. 1990, 29, 3680-3685.
    82017
  24. Bruno, J. W.; Huffman, J. C.; Green, M. A.; Zubkowski, J. D.; Hatfield, W. E.; Caulton, K. G.: Simultaneous Photodissociation of H2 and PMe2Ph from OsH4(PMe2Ph)3: Production of Dimeric and Paramagnetic Osmium Polyhydrides.  Organometallics. 1990, 9, 2556-2567.
    83023, 82025, 83020
  25. Chisholm, M. H.; Hammond, C. E.; Huffman, J. C.; Martin, J. D.: Twelve-Electron Tetranuclear Tungsten Alkoxide Clusters are Not Tetrahedral. Preparation, Structure and Bonding in W4(O)(OPri)10 and W4(O)(C1)(OPri)9. Comparisons with the Bonding in Carbonyl Clusters.  Polyhedron. 1990, 11, 1829-1842.
    89034
  26. Marinelli, G.; Streib, W. E.; Huffman, J. C.; Caulton, K. G.; Gagne, M. R.; Takats, J.; Dartiguenave, M.; Chardon, C.; Jackson, S. A.; Eisenstein, O.: The Origin of Structural Variety of Alkyne Complexes of d8 Metals. An Example of Structural Isomerism. Polyhedron. 1990, 11, 1867-1881.
    88115, 87815, 87816
  27. Chisholm, M. H.; Folting, K.; Johnston, V. J.; Hammond, C. E.: A tricarbonyl, tetranuclear tungsten cluster supported by alkoxide ligands: W4(OCH2Pri)12 (.eta.2, ?4-CO)(CO)2. J. Organomet. Chem. 1990, 394, 265-274.
    89134
  28. Chisholm, M. H.; Hammond, C. E.; Huffman, J. C.; Johnston, V. J.: Structural characterization of a tetranuclear tungsten carbide cluster formed by the reductive cleavage of carbon monoxide: W4(.mu.4-C)(OCH2-c-C5H9)14.  J. Organomet. Chem. 1990, 394, C16-C20.
    89147
  29. Caulton, K. G.; Chisholm, M. H.; Drake, S. R.; Huffman, J. C.: Preparation, Crystal and Molecular Structure of a Hydrocarbon Soluble, Volatile Oxo-alkoxide of Barium: H4Ba6(.mu.6-O)(OCH2CH2OCH3)14.  J. Chem. Soc., Chem. Commun. 1990, 21, 1498-1499.
    90061
  30. Wark, T. A.; Gulliver, E. A.; Jones, L. C.; Hampden-Smith, M. J.; Rheingold, A. E.; Huffman, J. C.: Molecular Routes To Tin Oxides. Better Ceramics Through Chemistry IV. Materials Research Society. 1990, 180, 61-72.
    88907
  31. A Planar Oxocuprate(II) Array via Heterometallic Alkoxide Chemistry. Samuels, J. A.; Vaartstra, B. A.; Huffman, J. C.; Trojan, K. L.; Hatfield, W. E.; Caulton, K. G. J. Am. Chem. Soc. 1990, 112, 9623-9624.
    90011
  32. Cayton, R. H.; Checon, S. T.; Chisholm, M. H.; Huffman, J. C.: How Do Two C-C Double Bonds Add to One M-M Triple Bond? Structure and Bonding in Bis(.eta.2-ethylene)hexakis(neopentoxy)ditungsten.  Angew. Chem. Int. Ed. Engl. 1990, 29, 1026-1028.
    89071
  33. Chmielewski, M.; Zbigniew, K.; Dodziuk, H.; Suwinska, K.; Rosenbaum, D.; Duddeck, H.; Magnus, P. D.; Huffman, J. C.: Conformation of 2-C,1-N-carbonyl-2-deoxy-a-D-glycopyranosylamines.  Carbohydr. Res. 1990, 203, 183-194.
    87129, 87022
  34. Vaartstra, B. A.; Huffman J. C.; Streib, W. E.; Caulton, K. G.: Rational Construction of Mixed-metal alkoxides.  J. Chem. Soc., Chem. Commun. 1990, 1750-1751.
    89214, 89227
  35. Chisholm, M. H.; Huffman, J. C.; Parkin, I. P.; Streib, W. E.: Preparation and Characterization of M2(SeAr')6 and Mixed Ligand M2(OR)2(SeAr')4 species (M = Mo,W).  Polyhedron. 1990, 24, 2941-2953.
    89231, 89270, 89259, 89240, 89234
  36. Little, J. L.; Whitesell, M. A.; Kester, J. G.; Folting, K.; Todd, L. J.: Synthesis of Icosahedral Boranes Containing Bismuth.  Inorg. Chem. 1990, 29, 804-808.
    88135
  37. Chisholm, M. H.; Folting, K.; Klang, J. A.: Reductive Cleavage of Ketonic Carbon-Oxygen Bonds in the Reactions between Ketones and Ditungsten Hexaalkoxides. Structural Characterization of a Ditungsten ?-Prophylidene Derivative.  Organometallics. 1990, 9, 602-606.
    89002
  38. Chisholm, M. H.; Folting, K.; Klang, J. A.: Reactions between Benzophenone and Ditungsten Hexaalkoxides. Molecular Structure and Reactivity of W(OCH2-t-Bu)4(py)(.eta.2-OCPh2).  Organometallics. 1990, 9, 607-613.
    88055
  39. Thaler, E. G.; Folting K.; Caulton, K. G.: eta3-MeC(CH2PPh2)3/Rhodium Complexes Utilize Phosphine Arm Dissociation Mechanisms at 25oC.  J. Am. Chem. Soc. 1990, 112, 2664-2672.
    89103
  40. Caulton, K. G.; Chisholm, M. H.; Drake, S.R.; Folting, K.: Synthesis and Structural Characterization of the First Examples of Molecular Aggregates of Barium supported by Aryloxide and Alkoxide ligands: [HBa5(O)(OPh)9(thf)8] and [H3Ba6(O)(OBut)11(OCEt2CH2O)(thf)3](thf = tetrahydrofuran.  J. Chem. Soc., Chem. Commun. 1990, 1349-1351. 
    89244, 90026
  41. He, X.D.; Fernandez-Baeza, J.; Chaudret, B.; Folting, K.; Caulton, K. G.: Modification of the Reactivity of Polyhydrides with Lewis Acids. Synthesis and Reactivity of {IrH5[P(iC3H7)3]2}2Cu(CF3SO3) X-ray Crystal Structure of {IrH2(MeCN)2[P(iC3H7)3]2}(BF4).  Inorg. Chem. 1990, 29, 5000-5002.
    89249
  42. Chisholm, M. H.; DiStasi, V. F.; Streib, W. E.: Kinetic Control in the Alcoholysis Reaction Involving Hexakisdimethylamidodialuminium and Tert-Butanol. Preparation, Crystal and Molecular Structures of A1(OBut)3(HNMe2) and Al2(NMe2)(OBut)5.  Polyhedron. 1990, 9, 253-255.
    89138, 89151
  43. Drake S. R.; Streib, W. E.; Chisholm, M. H.; Caulton, K. G.: Facile Synthesis and Structural Principles of the Strontium Phenoxide Sr4(OPh)8(PhOH)2(THF)6.  Inorg. Chem. 1990, 29, 2707-2708.
    89265
  44. Vaartstra, B. A.; Streib W. E.; Caulton K. G.: C-O Bond Scission in Heterometallic Alkoxides: Formation and Structure of K4Zr2O(OiPr)10.  J. Am. Chem. Soc. 1990, 112, 8593-8595.
    89254, 89150
  45. Caulton, K. G.; Chisholm, M. H.; Drake, S.R.; Streib, W. E.: Synthesis and Structure of [Ba3(OSiPh3)6(THF)].O.5 THF, a Trinuclear Barium Siloxide Containing Low-Coordinate Barium Ions.  Angew. Chem. Int. Ed. Engl. 1990, 29, 1483-1485. 
    90170
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