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The numbers following each publication are linked to the structures reported in the publication.

2000
  1. Burkey, D.J.; Hanusa, T.B.; Huffman, J.C.: Stereochemical Activity of the Metal-Centered Lone Electron Pair in Group 14 Metallocenes. Crystal Structure of the Linear Sandwich Complex [C5(iPr)3H2]2Pb. Inorg. Chem. 2000, 39, 153-155.
    95999
  2. Burkey, D.J.; Hanusa, T.B.; Huffman, J.C.: Correction to Stereochemical Activity of the Metal-Centered Lone Electron Pair in Group 14 Metallocenes. Crystal Structure of the Linear Sandwich Complex [C5(iPr)3H2]2Pb. Inorg. Chem. 2000, 39, 1834.
    95999
  3. Brechin, E.K.; Knapp, M.J.; Huffman, J.C.; Hendrickson, D.N.; Christou, G.: New hexanuclear and octanuclear iron(III) oxide clusters: octahedral [Fe6O2]14+ species and core isomerism in [Fe8O4]16+ complexes. Inorg. Chim. Acta. 2000, 297, 389-399.
    98050, 98063, 98402, 99020
  4. Coalter, J.N.; Bollinger, J.C.; Huffman, J.C.; Werner-Zwanziger, U.; Caulton, K.G.; Davidson, E.R.; Gerard, H.; Clot, E.; Eisenstein, O.: Coordinated carbenes from electron-rich olefins on RuHCl(PPri3)2. New J. Chem. 2000, 24, 9-26.
    98022, 98069
  5. Chisholm, M.H.; Folting; K.F.; Glasgow, K.C.; Lucas, E.; Streib, W.E.: Reductive Cleavage of Aldehydes to Oxo—Alkylidene and Oxo—Alkylidyne Complexes in Their Reactions with W2(OCH2tBu)6(py)2. Organometallics. 2000, 19, 884-892.
    91102, 90200, 91117, 90210
  6. Caulton, K.G.; Gemer, C.; Huffman, J.C.; Kirchner, K.; Mauthner, K. J.: Solution and solid—gas reactivity of unsaturated [RuCp(tmeda)]+ (tmeda=Me2NC2H4NMe2). J. Organomet. Chem 2000, 594, 342-353.
    98109
  7. Chisholm, M.H.; Folting, K.; Huffman, J.C.; Li, H.; Macintosh, A.M.; Wu, D.: d3—d3 Diolates of dimolybdenum and ditungsten Part 4. Molybdenum derivatives of S(—)-1,1-diphenyl-1,2-propanediol, S(—)-1,1,2-triphenyl-1,2-ethanediol and (1R,2R)-(—)-1,2-dicyclohexyl-1,2-ethanediol. Polyhedron. 2000, 19, 375-380.
    97046, 97082
  8. Chisholm, M.H.; Huffman, J.C.; and Iyer, S.S.: Some studies of the substitution chemistry of [Rh2(OAc)2(CH3CN)4]-[BF4]2 with monodentate and bidentate tertiary phosphines. Dalton Trans. 2000, 1483-1489.
    95074, 95056
  9. Coalter, N.L.; Concolino, T.E.; Streib, W.E.; Hughes, C.G.; Rheingold, A.L.; Zaleski, J.M.: Structure and Thermal Reactivity of a Novel Pd(0) Metalloenediyne. J. Am. Chem. Soc, 2000. 122, 3112-3117.
    98211
  10. Yandulov, D.V.; Huang, D.J.; Huffman, J.C.; Caulton, K.G.: Structural Distortions in mer-M(H)3(NO)L2 (M=Ru, Os) and Their Influence on Intramolecular Fluxionality and Quantum Exchange Coupling. Inorg. Chem. 2000, 39, 1919-1932.
    99009
  11. Huang, D.; Streib, W.E.; Eisenstein, O.; Caulton, K.G.: 16-Electron Ruthenium(0) Complexes Containing the Ru(NO)L2+ Substructure: Planar RuCH3(NO)L2 vs Sawhorse [Ru(NO)(C═C(SiMe3)2L2]+. Organometallics. 2000, 19, 1967-1972.
    99038
  12. Romain, J.K.; Ribblett, J.W.; Byrn, R.W.; Snyder, R.D.; Storhoff, B.N.; Huffman, J.C.: Synthesis and Properties of Phenyl Phosphines with Meta-Positioned Methyl Groups and the X-ray Structure of Tris(3,5-dimethyl-4-methoxyphenyl)phosphine. Organometallics., 2000, 19, 2047-2050.
    99904
  13. Chisholm, M.H.; Iyer, S.S.; Streib, W.E.: Chiral C2 and C1 symmetric (cyclooctane-1,5-diyl)bis(2-pyrazolyl)borate complexes of potassium and thallium. Preparation, structures and solution behavior. New J. Chem. 2000, 24, 393-398.
    98410, 98106, 98102, 98047
  14. Huang, D.; Bollinger, J.C.; Streib, W.E.; Folting, K.; Young, Jr., V.; Eisenstein, O.; Caulton, K.: A 14-Electron Ruthenium(II) Hydride, [RuH(CO)(PtBu2Me)2]BAr′4 (Ar′=3,5-(C6H3)(CF3)2): Synthesis, Structure, and Reactivity toward Alkenes and Oxygen Ligands. Organometallics. 2000, 19, 2281-2290.
    99012
  15. Yoo, J.; Brechin, E.K.; Yamaguchi, A.; Nakano, M.; Huffman, J.C.; Maniero, A.L.; Brunel, L.; Awaga, K.; Ishimoto, H.; Christou, G.; Hendrickson, D.Single-Molecule Magnets: A New Class of Tetranuclear Manganese Magnets. Inorg. Chem. 2000, 39, 3615-3623.
    98149
  16. Chisholm, M.H.; Macintosh, A.M.; Huffman, J.C.; Wu, D.; Davidson, E.; Clark, R.J.H.; Firth, S.: Dimolybdenum Bis((S,S,S,)-triisopropanolaminate(3—)): A Blue Compound with an Unusual Mo—Mo Triple Bond. Inorg. Chem. 2000, 39, 3544-3550.
    98138
  17. Coalter, III, J.N.; Huffman, J.C.; Streib, W.E.; Caulton, K.G.: A New Class of Electron-Rich Unsaturated Molecules: Ru2HnX4-n(PiPr3)4, X=Anion. Inorg. Chem. 2000, 39, 3757-3764.
    98193, 98008, 98141, 98190
  18. Coalter, III, J.N.; Streib, W.E.; Caulton, K.G.: Reactivity of [RuHCl(PiPr3)2]2 with Functionalized Vinyl Substrates. The H2 Ligand as a Sensitive Probe of Electronic Structure. Inorg. Chem. 2000, 39, 3749-3756.
    98081
  19. De Sousa, A.P.G.; Silva, R.M.; Cesar, A.; Wardell, J.L.; Huffman, J.C.; Abras, A. J.: Structures, semi-empirical calculations and thermolyses of some five- and six-membered chelateorganotin mercaptide complexes. J. Organomet. Chem. 2000, 605, 82-88.
    97075, 97073
  20. Huang, D.; Koren, P.R.; Folting, K.; Davidson, E.R.; Caulton, K.G.: Facile and Reversible Cleavage of C—F Bonds. Contrasting Thermodynamic Selectivity for Ru—CF2H vs F—Os═CFH. J. Am. Chem. Soc. 2000, 122, 8916-8931.
    97004
  21. Seddon, E.J.; Yoo, J.; Folting, K.; Huffman, J.C.; Hendrickson, D.N.; Christou, G.:Dinuclear and hexanuclear iron(III) carboxylate clusters with a bis(bipyridine) ligand: supramolecular aggregation of [Fe2O2] unites to give a [Fe6O6] ladder structure.Dalton Trans. 2000, 20, 3640-3648.
    98127, 98075, 98140, 99001, 98201
  22. Coalter, III, J.N.; Huffman, J.C.; Caulton, K.G.: Cleavage of H—C(sp2) and c(sp2)—X Bonds (X═Alkyl, Aryl, OR, NR2): Facile Decarbonylation, Isonitrile Abstraction, or Dehydrogenation of Aldehydes, Esters, Amides, Amines, and Imines by [RuHCl(PiPr3)2]2. Organometallics. 2000, 19, 3569-3578.
    00008, 00011
  23. Gottschalk-Gaudig, T.; Huffman, J.C.; Gérard, H.; Eisenstein, O.; Caulton, K.G.: Unsaturated Ru(0) Species with a Constrained Bis-Phosphine Ligand: [Ru(CO)2(tBu2PCH2CH2PtBu2)]2. Comparison to [Ru(CO)2(PtBu2Me)2]. Inorg. Chem. 2000, 39, 3957-3962.
    98144
  24. Santos, E.C.; Pinkerton, A.B.; Kinkead, S.A.; Hurlburt, P.K.; Jasper, S.A.; Sellers, C.W.; Huffman, J.C.; Todd, L.J.:Syntheses of nido-9,11,X2-7,8-C2B9H10- anions (X═Cl, Br or I) and the synthesis and structural characterization of N(C2H5)4[commo-3,3’-Co(4,7-Br2-3,1,2-CoC2B9H9)2]. Polyhedron. 2000, 19, 1777-1781.
    96109
  25. Chisholm, M.H.; Click, D.R.; Huffman, J.C.: Further Studies on the Substitutional Behavior of 1,2-Mo2Br2(CH2SiMe3)4. Alkyl, Amide, Phosphide, Alkoxide, and Thiolate for Bromide Exchange and Isomerizations of 1,1- and 1,2-Mo2X2(CH2SiMe3)4 Compounds.Organometallics. 2000, 19, 3916-3924.
    99094
  26. Boskovic, C.; Folting, K.; Christou, G.: Tetranuclear manganese carboxylate clusters with imizadole-carboxylate chelating ligands. X-ray crystal structure of the 4-imizadoleacetate complex. Polyhedron. 2000, 19, 2111-2118.
    99065
  27. Xu, F.; Reamer, R.A.; Tillyer, R.; Cummins, J.M.; Grabowski, E.J.J.; Reider, P.J.; Collum, D.B.; Huffman, J.C.: Highly Enantioselective 1,2-Addition of Lithium Acetylide-Ephedrate Complexes: Spectroscopic Evidence for Reaction Proceeding via a 2:2 Tetramer, and X-ray Characterization of Related Complexes.J. Am. Chem. Soc. 2000, 122, 11212-11218.
    97902, 97903
  28. Gashti, A.N.; Huffman, J.C.; Edwards, A.; Szekeley, G.; Siedle, A.R.; Karty, J.A.; Reilly, J.P.; Todd, L.J.: Fluorination studies of the [commo-3,3’-Co(3,1,2-CoC2B9H11)2-1]ion. J. Organomet. Chem 2000, 614, 120-124.
    99085
  29. Chisholm, M.H.; Click, D.R.; Huffman, J.C.:Octakis(trimethylsilylmethyl)dioxotetramolybdenum.A novel tetranuclear compound with two localized metal—metal triple bonds. J. Organomet. Chem, 2000, 614, 238-242.
    99022
  30. Seddon, E.J.; Huffman, J.C.; Christou, G.:A new core topology in hexanuclear iron(III) carboxylate chemistry: [Fe6O3(O2CMe)9(OEt)2(bpy)2](ClO4). Dalton Trans. 2000, 4446-4452.
    99057
  31. M Chisholm, M.H.; Eilerts, N.W.; Huffman, J.C.; Iyer, S.S.; Pacold, M.; Phomphrai, K.:olecular Design of Single-Site Metal Alkoxide Catalyst Precursors for Ring-Opening Polymerization Reactions Leading to Polyoxygenates. 1. Polylactide Formation by Achiral and Chiral Magnesium and Zinc Alkoxides, (η3-L)MOR, WhereL=Trispyrazolyl- and Trisindazolylborate Ligands. J. Am. Chem. Soc. 2000, 122, 11845-11854.
    97089, 97118, 99115, 96037
  32. Yandulov, D. V.; Huang, D. J.; Huffman, J. C.; Caulton, K. G.:Structural distortions in mer-M(H)(3)(NO)L-2 (M = Ru, Os) and their influence on intramolecular fluxionality and quantum exchange coupling.Inorg. Chem.2000, 39(9), 1919-1932.
    99009
  33. Wang, S. Y.; Wemple, M. S.; Yoo, J.; Folting, K.; Huffman, J. C.; Hagen, K. S.; Hendrickson, D. N.; Christou, G.:Tetranuclear manganese carboxylate complexes with a trigonal pyramidal metal topology via controlled potential electrolysis.Inorg. Chem.2000, 39(7), 1501-1513.
    89203, 89242, 94358
  34. Gemel, C.; Folting, K.; Caulton, K. G.:New approach to Ru(II) pincer ligand chemistry. Bis(tert- butylaminomethyl)pyridine coordinated to ruthenium(II). Inorg. Chem.2000, 39(7), 1593-1597. 99011
  35. Coalter, J. N.; Bollinger, J. C.; Eisenstein, O.; Caulton, K. G.:R-Group reversal of isomer stability for RuH(X)L-2(CCHR) vs. Ru(X)L-2(CCH2R): access to four-coordinate ruthenium carbenes and carbynes.New J. Chem.2000, 24(12), 925-927.
    01087
  36. Chisholm, M. H.; Folting, K.; Huffman, J. C.; Li, H.; Macintosh, A. M.; Wu, D. D.:d(3)-d(3) Diolates of dimolybdenum and ditungsten Part 4. Molybdenum derivatives of S(-)-1,1-diphenyl-1,2-propanediol, S(-)-1,1,2-triphenyl-1,2-ethanediol and (1R, 2R)-(-)-1,2- dicyclohexyl-1,2-ethanediol.Polyhedron.2000, 19(4): 375-380.
    97046

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