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The numbers following each publication are linked to the structures reported in the publication.

1987
  1. Chisholm, M. H.; Hammond, C. E.; HampdenSmith, M.; Huffman, J. C.; Van der Sluys, W. G.: Preparation and Structure of [Mo4(OMe)2(OisoPr)10]; Comments on why [W2(OisoPr)6] Dimerizes Whereas [Mo2(OisoPr)6] Does Not. Angew. Chem. Intl. Ed. Engl. 1987, 26, 904-906.
    87076
  2. Heterometallic Polyhydride Raft Formation: A Comparison of Syntheses Using Alkoxides of Copper and Gold. Sutherland, B. R.; Ho, D. M.; Huffman, J. C.; Caulton, K. G. Angew. Chem. Intl. Ed. Engl. 1987, 26, 135-137.
    86043, 86077
  3. Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, HR.; Hendrickson, D. N.: Salicylate Mediated Assembly of the Discrete Mixed Valence Nonanuclear Manganese Complex [Mn9O4(O2CPh)8(sal)4(salH)2(py)4](salH2 = Salicylic Acid, py = Pyridine). Angew. Chem. Intl. Ed. Engl. 1987, 26, 915-916.
    86109
  4. Christou, G.; Vincent, J. B.; Bashkin, J. S.; Christmas, C.; Huffman, J. C.: Synthesis of Tetranuclear Manganese Complexes as Models of the Photosynthetic Water Oxidation Site. Rec. Trav. Chim. PaysBas, 1987, 106, 217.
    86084
  5. Chisholm, M. H.; Hammond, C. E.; Huffman, J. C.: Molybdenum Hexadimethylamide. J. Chem. Soc., Chem. Commun. 1987, 1423-1424.
    87079
  6. Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, HR.; Hendrickson, D. N.: Support from Model Studies for the Proposed Existence of an S1 Oxidation Level in the Manganese Assembly of the Photosynthetic Water Oxidation Centre. J. Chem. Soc., Chem. Commun. 1987, 1303-1305.
  7. Seela, J. L.; Huffman, J. C.; Christou, G.: The First Example of a NiobiumSulphideThiolate Cluster: MetalMetal Bonding and .mu.4Sulphide Groups in Tetranuclear [Nb4S2(SPh)12]4. J. Chem. Soc., Chem. Commun. 1987, 1258-1260.
    86130
  8. Buhro, W. E.; Chisholm, M. H.; Folting, K.; Eichhorn, B. W.; Huffman, J. C.: The First Example of a d3d3 Dinuclear Compound containing Fourco ordinate Metal Atoms sharing a Pair of Bridging Ligands: [(ButO)2W(.mu.PPh2)]2. J. Chem. Soc., Chem. Commun. 1987, 845-847.
    86171
  9. McCarthy, J. R.; Barney, C. L.; O'Donnell, M. J.; Huffman, J. C.: New Pathway for the Reaction of Difluorocarbene with Imines. J. Chem. Soc., Chem. Commun. 1987, 469-470.
    84707
  10. Vincent, J. B.; Christmas, C.; Huffman, J. C.; Christou, G.; Chang, HR.; Hendrickson, D. N.: Modelling the Photosynthetic Water Oxidation Centre: Synthesis, Structure and Magnetic Properties of [Mn4O2(OAc)7(bipy)2](ClO4.3H2O (bipy = 2,2'Bipyridine). J. Chem. Soc., Chem. Commun. 1987, 236-238.
    86084
  11. Chisholm, M. H.; Huffman, J. C.; Pasterczyk, J. W.: 1,2Bis(ditertbutylarsenido)tetrakis(dimethyl-amido)dimolybdenum and ditungsten. Synthesis, Structures, and Solution Behavior. Inorg. Chem. 1987, 26, 3781-3785.
    86095, 86126
  12. Cai, S.; Hoffman, D. M.; Huffman, J. C.; Wierda, D. A.; Woo, HG.: Synthesis and Structural Characterization of [Re2(.mu.O)2O2(CH2CMe3)4] and the Li+ and [NEt4]+ Salts of the d2 [ReO2(CH2CMe3)2] Anion. Inorg. Chem. 1987, 26, 3693-3700.
    85807, 85897, 86804, 87901
  13. Chisholm, M. H.; Eichhorn, B. W.; Folting, K.; Huffman, J. C.; Ontiveros, C. D.; Streib, W. E.; Van Der Sluys, W. G.: Preparation and Characterization of Na2W2Cl7(THF)5. A Synthetically Useful Precursor for X3W.tplbnd.WX3 Compounds Where X = CH2tBu, NMe2, and OtBu. Inorg. Chem. 1987, 26, 3182-3186.
    86113
  14. Buhro, W. E.; Chisholm, M. H.; Folting, K.; Huffman, J. C.: Phosphinecarboxylate Ligands Formed by the Insertion of Carbon Dioxide into MetalPhosphido Bonds. Preparation and Structural Characterization of Tetrakis(ditertbutylphosphinecarboxylato)dimolybdenum. Inorg. Chem. 1987, 26, 3087-3088.
    87035
  15. Nicholson, J. R.; Huffman, J. C.; Ho, D. M.; Christou, G.: Direct Synthesis of VE2+ (E = S, Se) Complexes Using Elemental Chalcogens. Preparation, Structure, and Properties of [VS(SPh)4]2 and [VSe(edt)2]2 (edt2 = Ethane1,2dithiolate). Inorg. Chem. 1987, 26, 3030-3034.
    86022, 86115
  16. Leutkens, M. L., Jr.; Hopkins, M. D.; Schultz, A. J.; Williams, J. M.; Fair, C. K.; Ross, F. K.; Huffman, J. C.; Sattelberger, A. P.: Synthesis, Characterization, LowTemperature (50 K) Neutron Diffraction Structure, and Reactivity of Chlorodihydridotetrakis(trimethylphosphine)tantalum(III). Inorg. Chem. 1987, 26, 2430-2436.
    83930
  17. Blatchford, T. P.; Chisholm, M. H.; Huffman, J. C.: Tris(N,N'dimethylethylenediaminato)dimolybdenum and Tris(N,N') dimethylethylenediaminato)ditungsten. A Comparison of Eclipsed and Staggered Triple Bonds, .sigma.2.pi.4, between Molybdenum and Tungsten Atoms in X3M.tplbnd.MX3 Compounds. Inorg. Chem. 1987, 26, 1920-1925.
    7965, 81058
  18. Money, J. K.; Folting, K.; Huffman, J. C.; Christou, G.: A Binuclear Vanadium(III) Complex Containing the Linear [VOV]4+ Unit: Preparation, Structure, and Properties of [V2O(SCH2CH2NMe2)4]. Inorg. Chem. 1987, 26, 944-948.
    86016
  19. Thaler, E.; Folting, K.; Huffman, J. C.; Caulton, K. G.: HCr[Me2PCH2)3CMe]2+BEt4: The First Synthesis of a Cationic Hydride Complex from HBEt3. Inorg. Chem. 1987, 26, 374-377.
    85105
  20. Hernandez, D. M.; Huffman, J. C.; Todd, L. J.: Synthesis and Crystal Structure of B10H10(C6H11)S(CH3)2CNH(tC4H9). Inorg. Chem. 1987, 26, 213-215.
    81015
  21. Lundquist, E. G.; Folting, K.; Huffman, J. C.; Caulton, K. G.: Conversion of Carbon Dioxide to Carbonate Using a Rhodium.mu.Hydroxy Species. Inorg. Chem. 1987, 26, 205-208.
    85148
  22. Paolini, J. P.; Palopoli, F. P.; Lendvay, L. J.; Huffman, J. C.: Pyrido[2',1':2,3]imidazo[4,5c]isoquinoline [1] and the Alkylation of Pyrido[2',1':2,3]imidazo[4,5c]isoquinolin5(6H)one. J. Heterocyclic Chem., 1987, 24, 549-553.
    83704, 83705
  23. Beshouri, S. M.; Fanwich, P. E.; Rothwell, I. P.; Huffman, J. C.: Synthesis and Crystal and Molecular Structures of M(OAr')2(CH2py6Me)2(M = Hf, Th; OAr' = 2,6Ditertbutylphenoxide; CH2py6Me = 2(6 Methylpyridyl)methyl), Complexes Containing Two C,NChelating PyridylMethyl Ligands. Organometallics. 1987, 6, 2498-2502.
    86904
  24. Cai, S.; Hoffman, D. M.; Lappas, D.; Woo, HG.; Huffman, J. C.: Synthesis and Structure of ReO(PMe3)(CH2SiMe3)3 and Reaction with Carbon Monoxide. Organometallics. 1987, 6, 2273-2278.
    85804
  25. Hessen, B.; Lemmen, T. H.; Luttikhedde, H. J. G.; Teuben, J. H.; Petersen, J. L.; Huffman, J. C.; Jagner, S.; Caulton, K. G.: Paramagnetic Monocyclopentadienyl Hydrocarbyl and Borohydride Compounds of Vanadium(II) and Vanadium(III): Synthesis, Structure, and Reactivity. Organometallics. 1987, 6, 2354-2362.
    84071
  26. Chisholm, M. H.; Eichhorn, B. W.; Huffman, J. C.: W2(nPr)2(.eta.2C2Me2)2(OiPr)4, W2(.mu.C2Me2)2(OiPr)4, and W4(.mu.CEt)2(.mu.C2Me2)2(.eta.2C2Me2)2(OiPr)4. Competitive .alpha. and .beta.CH Activation Pathways at a Dimetal Center. Organometallics. 1987, 6, 2264-2265.
    87042, 87050
  27. Larson, E. J.; Van Dort, P. C.; Dailey, J. S.; Lakanen, J. R.; Pederson, L. M.; Silver, M. E.; Huffman, J. C.; Russo, S. O.: Thermally Stable Allyl Zirconium Halide Compounds. Synthesis, Crystal Structure and Dynamics of (.eta.5C5Me5)(.eta.31,2,3Me3allyl)ZrBr2 and (.eta.5C5Me5)(.eta.31,1,2Me3allyl)ZrBr2. Organometallics. 1987, 6, 2141-2146.
    86817, 86820
  28. Chisholm, M. H.; Clark, D. L.; Ho, D.; Huffman, J. C.: Monoisocyanide Adducts of Ditungsten Hexaalkoxides. Synthetic, Structural, and Theoretical Investigations into the Nature of C=N Bond Order Reduction. Organometallics. 1987, 6, 1532-1542.
    86032, 86050
  29. Holl, M. M.; Hillhouse, G. L.; Folting, K.; Huffman, J. C.: Synthesis and Reactivity of a Neutral Tungsten(0) Alkyl Complex. Insertion of CO2 into the WCH3 Bond of trans, transW(CH3)(CO)2(NO)(PPh3)2 and the Structural Characterization of transW(.eta.2 O2CCH3)(CO)(NO)(PPh3)2. Organometallics. 1987, 6, 1522-1527.
    86912
  30. Chisholm, M. H.; Clark, D. L.; Huffman, J. C.; Smith, C. A.: Metal AlkoxidesModels for Metal Oxides. 12. The First Molecular Carbido Cluster of Tungsten W4(C)(NMe)(OiPr)12 and 13C NMR Spectoscopic Evidence for a Related OxoCarbido Cluster, W4(C)(O)(OiPr)12, Formed in the Stepwise Reductive Cleavage of Carbon Monoxide by Lower Valent Tungsten Alkoxides. Organometallics. 1987, 6, 1280-1291.
    82019
  31. Chisholm, M. H.; Huffman, J. C.; Marchant, N. S.: Preparation, Structure, and Bonding of Mo2(OCH2CMe3)6(.mu..eta.1,.eta.2NCNMe2). Organometallics. 1987, 6, 1073-1080.
    83041
  32. Beshouri, S. M.; Fanwick, P. H.; Rothwell, I. P.; Huffman, J. C.: Observation of a Facile Isomerization of an EarlyTransitionMetal .eta.2Iminoacyl Group via a 1,2Hydrogen Shift. Organometallics. 1987, 6, 891-893.
    86917
  33. Chisholm, M. H.; Hammond, C. E.; Huffman, J. C.: Mo3[C(O)NMe2]6(CO)6(HNMe2)2. An Unexpected Product Formed in the Carbonylation of Mo(NMe2)4 Displaying Three Distinct Modes of Carbamoyl Molybdenum Bonding. Organometallics. 1987, 6, 210-211.
    85116
  34. Hazin, P. H.; Huffman, J. C.; Bruno, J. W.: Synthetic and Structural Studies of Pentamethylcyclopentadienyl Complexes of Lanthanum and Cerium. Organometallics. 1987, 6, 23-27.
    86803
  35. Chisholm, M. H.; Huffman, J. C.; Pasterczyk, J. W.: Synthesis and Reactivity of Compounds of Formula W(S)(OR)4. Polyhedron. 1987, 6, 15511557.
    85013
  36. Blatchford, T. P.; Chisholm, M. H.; Huffman, J. C.: Diamagnetic anisotropy of M.tplbnd.M Bonded Molecules for M = Mo or W: How Much .pi. is there and how do we slice it? Polyhedron. 1987, 6, 16771680.
  37. Chesnut, R. W.; Durfee, L. D.; Fanwick, P. E.; Rothwell, I. P.; Folting, K.; Huffman, J. C.: The Chemistry of Sterically Crowded Aryloxide LigandsVII. Synthesis, Structure and Spectroscopic Properties of Some Group 4 and Group 5 Metal Derivatives of 2,6Diphenyloxide. Polyhedron. 1987, 6, 2019-2026.
    86916
  38. Nicholson, J. R.; Christou, G.; Huffman, J. C.; Folting, K.: The Synthesis, Structure and Spectroscopic Properties of the di and trinuclear Ni(II)thiolate Complexes. Polyhedron. 1987, 6, 863-870.
    85122, 85123
  39. Chisholm, M. H.; Ho, D. M.; Huffman, J. C.; Van der Sluys, W. G.: A Reaction Converting a WW Triple Bond to a Double Bond: Tetrakis diethyldithiophosphatedisulfideditungsten, Preparation and Characterization. Polyhedron.1987, 6, 1115-1123.
    86035
  40. Chisholm, M. H.; Conroy, B. K.; Eichhorn, B. W.; Folting, K.; Hoffman, D. M.; Huffman, J. C.; Marchant, N. S.: Reactions Involving Alkynes and Tungsten-Tungsten Triple Bonds Supported by Alkoxide Ligands. Polyhedron. 1987, 6, 783-792.
    8066, 82009, 83019, 84040
  41. Scioly, A. J.; Luetkens, M. L., Jr.; Wilson, R. B., Jr.; Huffman, J. C.; Sattelberger, A. P.: Synthesis and Characterization of Binuclear Tantalum Hydride Complexes. Polyhedron. 1987, 6, 741-757.
    82504, 82901
  42. Chisholm, M. H.; Clark D. L.; Folting, K.; Huffman, J. C.; HampdenSmith, M.: Hexaisopropoxyditungsten and Dodecaisopropoxytetratungsten: W2(OiPr)6 and W4(OiPr)12. 1. Preparation, Structure, and Bonding. The First Example of a MetalMetal Triple Bond and Its 12Electron Cluster. Analogies with Ethyne and Cyclobutadiene. J. Am. Chem. Soc. 1987. 109, 7750-7761.
    86060
  43. Chisholm, M. H.; Clark, D. L.; Huffman, J. C.; Van Der Sluys, W. G.: The Tungsten-Tungsten Triple Bond. 14. Factors Influencing Triple Bonds between Tungsten Atoms having Valence Molecular Orbital Configurations of .omega.2.pi.4 and .pi.4.omega.2 and Preparation and Characterization of Bis(neopentyl)bis(acetato) -bis(diethyldithiocarbamato)ditungsten. J. Am. Chem. Soc. 1987, 109, 6817-6825.
    85098
  44. Chisholm, M. H.; Clark, D. L.; Huffman, J. C.; Van Der Sluys, W. G.; Kober, E. M.; Lichtenberger, D. L.; Bursten, B. E.: The TungstenTungsten Triple Bond. 13. Bisalkyl Tetracarboxylates of Dimolybdenum and Ditungsten. Triple Bonds between Metal Atoms with the Valence Molecular Orbital Description .pi.4.delta.2. J. Am. Chem. Soc. 1987. 109, 6796-6816.
    84005, 84210, 85022, 85055, 85057, 85132
  45. Bashkin, J. S.; Chang, HR.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. C.: Modelling the Photosynthetic Water Oxidation Center: Preparation and Physical Properties of a Tetranuclear Oxide Bridged Mn Complex Corresponding to the Native S2 State. J. Am. Chem. Soc. 1987. 109, 6502-6504.
    87008
  46. Chamberlain, L. R.; Kerschner, J. L.; Rothwell, A. P.; Rothwell, I. P.; Huffman, J. C.: Cyclometalation of 2,6Ditertbutylphenoxide Ligands by Tantalum Aryl Groups: Aliphatic CarbonHydrogen Bond Activation and Aryl Isomerizaton via Benzyne (oPhenylene) Intermediates. J. Am. Chem. Soc. 1987. 109, 6471-6478.
    82904
  47. Chamberlain, L. R.; Durfee, L. D.; Fanwick, P. E.; Kobriger, L. M.; Latesky, S. L.; McMullen, A. K.; Steffey, B. D.; Rothwell, I. P.; Folting, K.; Huffman, J. C.: Intramolecular Coupling of .eta.2Iminoacryl and .eta.2Acyl Functions at Group 4 and Group 5 Metal Centers: Structure and Spectroscopic Properties of the Resulting Enamidolate and Enediamide Complexes. J. Am. Chem. Soc. 1987. 109, 6068-6076.
    84916, 85924, 85925, 86903
  48. Vincent, J. B.; Chang, HR.; Folting, K.; Huffman, J. C.; Christou, G.; Hendrickson, D. N.: Preparation and Physical Properties of Trinuclear OxoCentered Manganese Complexes of the General Formulation [Mn3O(O2CR)6L3]0,+ (R = Me or Ph; L = a Neutral Donor Group) and the Crystal structures of [Mn3O(O2CMe)6(pyr)3](pyr) and [Mn3O(O2CPh)6(pyr)2(H2O)].0.5MeCN. J. Am. Chem. Soc. 1987. 109, 5703-5711.
    85096, 86033
  49. Montgomery, L. K.; Grendze, M. P.; Huffman, J. C.: The Molecular Structure of a Substituted 2Norbornyl Cation, 2Methoxy1,7,7trimethylbicyclo[2.2.1]hept2ylium Fluoroborate. J. Am. Chem. Soc., 1987. 109, 4749-4750.
    87401
  50. Durfee, L. D.; Fanwick, P. E.; Rothwell, I. P.; Folting, K.; Huffman, J. C.: Reductive Elimination Pathways to LowValent Titanium Aryloxide Complexes. J. Am. Chem. Soc. 1987. 109, 4720-4722.
    86919
  51. Sutherland, B. R.; Folting, K.; Streib, W. E.; Ho, D. M.; Huffman, J. C.; Caulton, K. G.: Synthetic and Mechanistic Features of Alcohol Elimination between Gold Alkoxides and Rhenium Polyhydrides. Metal Polyhedron Reconstruction upon Protonation. J. Am. Chem. Soc. 1987. 109, 3489-3490.
    86088, 86145
  52. Chisholm, M. H.; Folting, K.; Eichhorn, B. W.; Huffman, J. C.: The First Hydrocarbyl Trinuclear and Tetranuclear Clusters of Tungsten: W3O(CH2Ph)(OiPr)9 and W3O(R)2(OiPr)8 Where R = CH2Ph, Ph, and W4(p tolyl)2(OiPr)10. J. Am. Chem. Soc. 1987. 109, 31467.
    86112
  53. Buchwald, S. L.; Watson, B. T.; Huffman, J. C.: The Synthesis, Reactions, and Molecular Structure of ZirconoceneAlkyne complexes. J. Am. Chem. Soc. 1987. 109, 2544-2546.
    86815
  54. Chisholm, M. H.; Huffman, J. C.; Van Der Sluys, W. G.:An Unbridged Triple Bond Uniting d6 Mo(0) and d2 Mo(IV) Atoms: Mo2(O iPr)4(dmpe)2. J. Am. Chem. Soc. 1987. 109, 2514-2515.
    86158
  55. Money, J. K.; Huffman, J. C.; Christou, G.:Preparation and Structure of (NEt4)2[V4S2(SCH2CH2S)6] and Its Structural and Electronic Relationship to the LixVS2 Phases. J. Am. Chem. Soc. 1987. 109, 2210-2211.
    86062
  56. Buhro, W. E.; Chisholm, M. H.; Folting, K.; Huffman, J. C.: Comparison of the Relative .pi.Donor Abilities of Amido and Phosphido Ligands. 1,2Bis(ditert butylphosphido)tetrakis(dimethylamido)dimolybdenum and ditungsten: 1,2-M2(P(t-Bu)2)2(NMe2)4(M=M). J. Am. Chem. Soc. 1987. 109, 905-906.
    86036, 86085
  57. Chamberlain, L. R.; Durfee, L. D.; Fanwick. P. E.; Kobriger, L.; Latesky, S. L.; McMullen, A.K.; Rothwell, I. P.; Folting, K.; Huffman, J. C.; Streib. W. E.; Wang, R.: Synthesis, Structure, and Spectroscopic Properties of Early Transition Metal .eta.2Iminoacyl Complexes Containing Aryl Oxide Ligation. J. Am. Chem. Soc. 1987. 109, 390-402.
    83945, 84908, 85906, 85917, 86902
  58. Chisholm, M. H.; Ham mond, C. E.; HampdenSmith, M.; Huffman, J. C. and Van Der Sluys, W. G.: Preparation and Structure of [Mo4(OMe)2(OiPr)10], Comments on Why [W2(OiPr)6] Dimerizes, Whereas [Mo2(OiPr)6] Does Not. Angew. Chem. Intl. Ed. Engl. 1987, 26, 904-906.
    87076
  59. Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.R. and Hendrickson, D. N.: SalicylateMediated Assembly of the Discrete Mixed Valence Nonanuclear Manganese Complex [Mn9O4(O2CPh)8(sal)4(salH)2(py)4] (salH) = salicylic acid, py= pyridine). Angew. Chem. Intl. Ed. Engl. 1987, 26, 915-916.
    86109
  60. Weintraub, P. M.; Tiernan, P. L.; Huffman, J. C.: Heterocycles. 10. A Facile Synthesis of 7Hydroxy6,7dihydro5H pyrrolo[1,2,a]imidazole. J. Heterocyclic Chem. 1987, 24, 561-563
    84708
  61. Chamberlain, L. R.; Rothwell, I. P.; Folting, K.; Huffman, J. C.: The Synthesis and Structure of Group 5 Metal Alkyl and Alkylidene Complexes Containing 2,6dialkylphenoxide Ligands: Xray Crystal Structures of [Ta(OC6H3Me22,6)2(CH2Ph)3], [Ta(OC6H3Me22,6)4Me], and [Ta(OC6H3But22,6)2(=CHSiMe3)(CH2SiMe3)]. J. Chem. Soc., Dalton. Trans. 1987, 155-162.
    84920, 84940, 82907
  62. Chisholm, M. H.; Huffman, J. C.; Pasterczyk, J. W.: (.eta.3P3)W(OCH2But)3(HNMe2) Formed by Cleavage of the W.tplbnd.W Bond in the Reaction between W2(OCH2But)6(HNMe2)2 and P4. Inorg. Chim. Acta, 1987, 133. 17-18.
    85131
  63. Chisholm, M. H.; Folting, K.; Hampden-Smith, J.; Smith, C. A.: Preparation and Characterization of Hexacyclohexido- and Trispinacolato-ditungsten (M=M). A Comparison of Staggered and Eclipsed Ethane-like O3W=WO3 Units. Polyhedron. 1987, 6, 1747-1755.
    85040, 87004
  64. Blau, R. J.; Chisholm, M. H.; Folting, K.; Wang, R. J.: Reactions of Ditungsten Hexaalkoxides with Alkynylplatinum(II) Complexes: Formation of Heterometallic Dicarbido Complexes in Competition with Products Derived from Alkyne Metathesis. J. Am. Chem. Soc. 1987, 109, 4552-4560.
    85074
  65. Chisholm, M. H.; Folting, K.; Huffman, J. C.; Pastercyzk, J. W.: Heavier Main-group Atoms as Ligands to Transition-metal Centers. Proc. Ind. Acad. Sci., 1987, 97, 195-198.
    85013, 85131, 86095
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