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The numbers following each publication are linked to the structures reported in the publication.

1992
  1. Chacon, S. T.; Chisholm, M. H.; Eisenstein, O.; Huffman, J.C. Structure, Bonding, and Dynamic Behavior of Bis(.eta.2-ethylene)hexakis(neopentoxy)ditungsten. Studies of the Reversible Addition of C-C Double Bonds to a W-W Triple Bond. J. Am. Chem. Soc. 1992, 114, 8497-8509.
    89071
  2. Blackman, A. G., Huffman, J. C., Lobkovsky, E. B. Christou, G.: Synthesis and Structure of [Mn6O2(O2CPh)10(EtOH)4(HsO)].EtOH, a Manganese Aggregrate Containing Three Types of Benzoate Ligation. Isomeration in [Mn6O2(O2CPh)10] Complexes. Polyhedron. 1992, 11, 251-255.
    90259
  3. Cayton, R. H.; Chisholm, M. H.; Hampden-Smith, M. J.; Huffman, J. C.; Moodley, K. G.: The Tungsten-Tungsten Triple Bond. 18. Bridging and Terminal Allyl Ligands in Complexes of Formula W2(R)2(NMe2) Where R= C3H7 and C4H7. Polyhedron. 1992, 11, 3197-3210.
    88002, 88058
  4. Chisholm; M. H.; Folting, K.; Huffman, J. C.; Kramer, K. S.; Tatz, R. J.: Direct Observation of Ligand Migration in the Reversible Addition of Trimethylphosphine to 1,2-Mo2(CH2Ph)2(O-i-Pr)4 and Structural Characterization of (PMe3)(PhCH2)2(i-PrO)Mo:.Mo(O-i-Pr)3 and 1,2-Mo2(CH2Ph)2(O-i-Pr)4(dmpm), Where dmpm = Bis(dimethylphosphino)methane. Organometallics. 1992, 11, 4029-4036.
    84035, 90272
  5. Caulton, K. G.; Cayton, R. H.; Chisholm, M. H.; Huffman, J. C.; Lobkovsky, E. B.; Xue, Z.: Structure and Bonding of (.mu.-Dicarbido)hexa-tert-butoxyditungsten, (t-BuO)3W.tplbnd.C-C.tplbnd.W(O-t-Bu)3. Organometallics. 1992, 11, 321-326.
    1056
  6. Tesh, K. F.; Hanusa, T. P.; Huffman, J. C.; Huffman, C. J.: Structural Relationships between Mono- and Dimeric Bis(alkoxides) and Bis(aryloxides) of Calcium and Barium. X-ray Crystal Structures of M(OC6H2-t-Bu2-2,6-Me-4)2(THF)3.(THF) (M = Ca, Ba) and [Ca(.mu.-OR)(OR)(THF)]2·2(toluene) [R = C(C6H5)2CH2C6H4Cl-4]. Inorg. Chem. 1992, 31, 5572-5279.
    90909
  7. Bouwman, E.; Bolcar, M. A.; Libby, E.; Huffman, J. C.; Folting, K.; Christou, G. Tetranuclear Manganese(III)-Oxo-Carboxylate Compexes Possessing Terminal Phenoxide or Alkoxide Ligands. Inorg. Chem. 1992, 31, 5185-5192.
    90329, 91064
  8. Bouwman, E.; Huffman, J. C.; Lobkovsky, E. B.; Christou, G. C.; Tsai, H.; Hendrickson, D.N. A New Fluorinated Tetraalkoxide Ligand Derived from the Hydration of Hexafluoroacetylacetone. Inorg. Chem. 1992, 31, 4436-4438.
    91099, 91188
  9. Coan, P. S.; Huffman, J. C.; Caulton, K. G. Strategy for Synthesis of an Yttrium/Copper(I) Complex with an Oxo Ligand Environment. Inorg. Chem. 1992, 31, 4207-4209.
    91352
  10. Lewis, L. N.; Krafft, T. A.; Huffman, J. C. Crystal and Molecular Structure of a (Dibenzylidenaecetone)platinum Dimer with Partial Pt Occupancy. Inorg. Chem. 1992, 31, 3555-3557.
    90902
  11. Soloveichik, G. L.; Eisenstein, O.; Poulton, J. T.; Streib, W. E.; Huffman, J. C.; Caulton, K. G. Multiple Structural Variants of LnCuI(.mu.-X)2CuILn (n = 1,2). Influence of Halide on a "Soft" Potential Energy Surface. Inorg. Chem. 1992, 31, 3306-3312.
    91324, 91330
  12. Clark, D. L.; Watkin, J. G.; Huffman, J. C. Preparation and X-ray Crystal Structure of K[Nd(O-2,6-i-Pr2C6H3)4]: A One-Dimensional Chain of Lanthanide Aryloxide Anions Joined by Bis(.eta.6-arene)-Potassium Interactions. Inorg. Chem. 1992, 31, 1554-1556.
    91654
  13. Van Der Sluys, W. G.; Huffman, J. C.; Ehler, D. S.; Sauer, N. N.Dissolution of Uranium Metal Using Iodine and 2-Propanol. Synthesis and X-ray Crystal Structure of Tetraiodotetrakis(isopropoxo)bis(isopropanol)diuranium. Inorg. Chem. 1992, 31, 1316-1318.
    90607
  14. Chisholm, M. H.; Kramer, K.S.; Martin, J. D.; Huffman, J. C.; Lobkovsky, E. B.; Streib, W. E. The Tungsten-Tungsten Triple Bond. 19. Preparation and Characterization of W26+-Containing Compounds Supported by Amide/Alkoxide and Trifluoromethanesulfonate Ligands. Inorg. Chem. 1992, 31, 4469-4474.
    90183, 91013, 91180
  15. Rhodes, L. F.; Huffman, J. C.; Caulton, K. G. Heterometallic species containing Cp2MH2 (M = Mo and W) and Cu+ or Ag+ are inner sphere redox intermediates. Inorg. Chim. Acta. 1992, 200, 639-649.
    83102
  16. Montgomery, L. K.; Burgin, T.; Husting, C.; Tilley, L.; Huffman, J. C.; Carlson, K. D.; Dudek, J. D.; Yaconi, G. A.; Geiser, U.; Williams, J. M.: Synthesis and Characterization of Radical Cation Salts Derived From Tetraselenafulvalene and Bis(ethylenedithio)tetraselenafulvalene. Mol. Cryst. Liq. Cryst., 1992, 211, 283-288.
    91205
  17. Rhodes, L. F.; Bansemer, R. L.; Folting, K.; Huffman, J. C.; Caulton, K. G.: A heterometallic cluster with extreme hydride content: H24Cu6Re4(PPh3)82+. Inorg. Chim. Acta. 1992, 191, 31-34.
    87059
  18. Berg, J. M.; Clark, D. L.; Huffman, J. C.; Morris, D. E.; Sattelberger, A. P.; Streib, W. E.; Van Der Sluys, W. G.; Watkin, J. G.: Early Actinide Alkoxide Chemistry. Synthesis, Characterization and Molecular Structures of Thorium(IV) and Uranium(IV) Aryloxide Complexes. J. Am. Chem. Soc. 1992, 114, 10811-10821.
    88901, 88902, 90651, 90652
  19. Tesh, K. F.; Jones, B.D.; Hanusa, T. P.; Huffman, J. C.: Synthesis and Crystallographic Characterization of [CsHN(SiMe3)]4, a Cesium-Based Heterocubane. J. Am. Chem. Soc. 1992, 114, 6590-6591.
    91908
  20. Sockwell, S. C.; Hanusa, T.; Huffman, J. C.: Formation and Reactions of Mono- and Bis(peralkylcyclopentadienyl) Complexes of Calcium and Barium. The X-ray Crystal Structure of [(Me4EtC5)Ca(.mu.-NSiMe2CH2CH2SiMe2)]2. J. Am. Chem. Soc. 1992, 114, 3393-3399.
    90910
  21. Johnson, T. J.; Huffman, J. C.; Caulton, K. G.: Enhanced Reactivity from Noninnocent Behavior by an Alkoxide Ligand in Cp*RuP(OR):Toward the Mechanism of Alcohol Elimination. J. Am. Chem. Soc. 1992, 114, 2725-2726.
    91234
  22. Buhro, W. E.; Chisholm, M. H.; Folting, K.; Huffman, J. C.; Martin, J. D.; Streib, W. E.: The Tungsten-Tungsten Triple Bond. 17. Mixed Amido-Phosphido Compounds for Formula M2(PR2)2(NMe2)4. Comparisons of Amido and Phosphido Ligation and Bridged and Unbridged Isomers. J. Am. Chem. Soc. 1992,114, 557-570.
    89123, 89048, 87013, 86172, 86036, 86085
  23. Chisholm, M. H.; Huffman, J. C.; Lucas, E. A.; Sousa, A.; Streib, W. E.: On the Nature of the Olefination Reaction Involving Ditungsten Hexaalkoxides and Aldehydes or Ketones. J. Am. Chem. Soc. 1992, 114, 2710-2712.
    91102, 91330
  24. Hendrickson, D. N.; Christou, G.; Schmitt, G. C.; Libby, E. A.; Bashkin, J. S.; Wang, S.; Tsai, H.; Vincent, J. B.; Boyd, P. D.W.; Huffman, J. C.; Folting, K.; Li, Q.; Streib, W. E.: Photosynthetic Water Oxidation Center: Spin Frustration in Distorted Cubane MnIVMnIII3 Model Complexes. J. Am. Chem. Soc. 1992, 114, 2455-2471.
    88072, 87171, 87008, 87082
  25. Reynolds, J. G.; Sendlinger, S.C.; Murray, A. M.; Huffman, J. C.; Christou, G.: Pyridine-2-thiolato Complexes of VII, VIII, and VIV with Unusual Structural Features. Angew. Chem. Int. Ed. Engl. 1992, 31, 1253-1255.
    92011, 91014, 91150
  26. Perlepes, S. P.; Huffman, J. C.; Christou, G.: Preparation and Characterization of Dinuclear Copper(II) Complexes Containing the [Cu2(.mu.-OAc)2]2+ Core. Polyhedron. 1992, 11, 1471-1479.
    90044, 90162
  27. Clark, D. L.; Huffman, J. C.; Watkin, J. G.: The First Structurally Characterised Homoleptic Thorium Alkoxide: X-Ray Crystal Structure of [Th(OCHPri2)4]2, and NMR Evidence For a Monomer-Dimer Equilibrium.J. Chem. Soc., Chem. Commun.1992, 266-268.
    91652
  28. Cayton, R. H.; Chisholm, M. H.; Putilina, E. F.; Folting, K.; Huffman, J. C.; Moodley, K. G.: Synthesis and Substitution Reactions of Dinuclear Molybdenum Complexes Containing Mo-Mo Quadruple Bonds and Labile Solvent Ligands. Inorg. Chem. 1992, 31, 2928-2934.
    91183, 90075, 90273
  29. McGeary, M. J.; Cayton, R. H.; Folting, K.; Huffman, J. C.; Caulton, K. G.: Potassium Triphenylsiloxide -"ate" Compounds of Tin(II): Molecular and Separated Ion Forms and Variable Potassium Coordination Numbers. Polyhedron. 1992, 11, 1369-1382.
    89229, 89191, 89212
  30. Chisholm, M. H.; Jansen, R. M.; Huffman, J. C. Organometallics. 1992, 11, 2305-2307.
    90059
  31. Reaction of organocalcium and -barium complexes with pyrazines. X-ray structural characterization of [(Me5C5)2Ba]2 (.mu.-C4H4N2). Williams, R. A.; Hanusa, T. P.; Huffman, J. C.: Attempted Preparation of a Dimetallabenzyne. Preparation and Crystal Structure of W2(.mu.-C3Ph3)(.mu.-CPh)(NMe2)4 (M-M). J. Organomet. Chem. 1992, 429, 143-152.
    88805
  32. Chisholm, M. H.; Hammond, C. E.; Johnston, V. J.; Streib, W. E.; Huffman, J. C.: Reductive Cleavage of Carbon Monoxide to Carbide and Oxide by Ditungsten and Tetratungsten Alkoxides. Crystal and Molecular Structures of W4(.mu.4-C)(OCH2-c-Pen)14, W4(.mu.4-C)(O)(OCH2-t-Bu)12, and W4(.mu.4-C)(O)(O-i-Pr)12. J. Am. Chem. Soc. 1992, 114, 7056-7065.
    89147, 91002, 91199
  33. Chisholm, M.H.; Cook, C.M.; Folting, K., Streib, W.E.: Oxygen atom transfer in the reaction between hexakis (dimethyl-tert-butylsiloxy) ditungsten and nitric oxide. A remarkable difference in the reactivity of the tungsten-tungsten triple bond as a function of the attendant ligands: ButO versus ButMe2SiO. Inorg. Chim. Acta. 1992, 198-200, 63-77.
    90038, 90112, 90280, 91172
  34. Schake, A.R.; Tsai, H.; de Vries, N.; Webb, R.J.; Folting, K.; Hendrickson, D.N.; Christou, G.: Variation in the Electron Count and Ground State of [Mn12O12 (O2CR)16(H2O)4] (R=Me or Ph) by Metal Substitution and Redox Changes: Preparation and Properties of [Mn8Fe4O12(O2CMe)16(H2O)4] · 4H2O · 2 MeCO2H and [NPrn4][Mn12O12(O2CPh)16(H2O)4] · H2O. J. Chem. Soc., Chem. Commun. 1992, 181-183.
    89145
  35. Chisholm, M.H.; Folting, K.; Putilina, E.F.: Mo2(ß-diketonate)4 Complexes. Preparations, Properties, and Solid-State and Molecular Structure of Tetrakis (2, 2, 6, 6-tetramethyl-3, 5-heptanedionato) dimolybdenum. Inorg. Chem. 1992, 31, 1510-1513.
    91038
  36. Chisholm, M.H.; Cook, C.M.; Folting, K.: A New Structural Type for an Electron-Precise, Six-Electron Triangular Metal Cluster: W3O2(O-tert-Bu)8. J. Am. Chem. Soc. 1992, 114, 2721-2722.
    91143
  37. Chapman, R.W.; Kester, J.G.; Folting, K.; Streib, W.E.; Todd, L.J.: Synthesis and Chemistry of B11H11Sn2- and Its Germanium and Lead Analogues. Crystal Structure of [B11H11SnCH3]PPh3CH3 · CH2Cl2. Inorg. Chem. 1992, 31, 979-983.
    87158
  38. Poulton, J.T.; Folting, K.; Caulton, K.G.: Reversible Dehydrogenation of a Heterobimetallic Polyhydride Compound. Organometallics. 1992, 11, 1364-1372.
    90057
  39. Drake, S.R.; Streib, W.E.; Folting, K.; Chisholm, M.H.; Caulton, K.G.: Dinuclear Barium Alkoxides and Siloxides Displaying Variable Coordination Numbers and Asymmetric Dispositions of Ligands. Inorg. Chem. 1992, 31, 3205-3210.
    90243, 90245
  40. McGeary, M.J.; Wedlich, R.C.; Coan, P.S.; Folting, K.; Caulton, K.G.: Synthesis and Thermal Decomposition of Copper (I) Silyloxide Complexes. X-Ray Crystal Structures of [Cu(OSiPh3)]4 and [Cu(OSiPh3)(PMe2Ph)]2. Polyhedron. 1992, 11, 2459-2473.
    91233, 91263
  41. Bianchini, C.; Caulton, K.G.; Folting, K.; Meli, A.; Peruzzini, M.; Polo, A.; Vizza, F.: Stepwise Metal-Assisted Reduction of .eta.4-coordinated Benzene to Cyclohexene. J. Am. Chem. Soc. 1992, 114, 7290-7291.
    91264
  42. Poulton, J.T.; Folting, K.; Streib, W.E.; Caulton, K.G.: Spectroscopic Assessment of the Degree of pi-Stabilization of Unsaturation in RuH (X) CO (PtBu2Me)2. Inorg. Chem. 1992, 31, 3190-3191.
    92001
  43. Perlepes, S.P.; Libby, E.; Streib, W.E.; Folting, K.; Christou, G.: The Reactions of Cu2(O2CMe)4(H2O)2 with 2,2’-bipyridine (bpy): Influence of the Cu:bpy Ratio, and the Structure of a Linear Polymer Comprising Two Alternating Types of Cu2 Units. Polyhedron. 1992, 8, 923-936.
    89094, 90034
  44. Parkin, I.P.; Folting, K.: Homoleptic Optically Active Ditungsten and Dimolybdenum Alkoxides. The Crystal Structure of (+) [W2-(OC10H19)6]. Dalton Trans. 1992, 2343-2352.
    90369
  45. Chisholm, M.H.; Kramer, K.S.; Streib, W.E.: W6(H)5(O-iPr)13. A Polynuclear Polyhydride Supported Exclusively by Alkoxide Ligands. J. Am. Chem. Soc. 1992, 114, 3571-3573.
    91285, 95498
  46. Chisholm, M.H.; Johnston, V.J.; Eisenstein, O.; Streib, W.E.: Synthesis, Structure, and Bonding of [CpCoW2(OCH2tBu)6], and Comments on the Combining Properties of CO and CpCo. Angew. Chem. Int. Ed. Engl. 1992, 31, 896-898.
    91255
  47. Wang, S.; Tsai, J.; Streib, W.E.; Christou, G.; Hendrickson, D.N.: High Nuclearity Molecular Species Exhibiting Spin Frustration; Fusion of Two MnIII4O2 Butterfly Complexes to yield an Intermediate Spin Ground State Mn III 7O4 Complex. J. Chem. Soc., Chem. Commun. 1992, 677-679.
    90077
  48. Wang, S.; Tsai, H.; Streib, W.E.; Christou, G.; Hendrickson, D.N.: Bromide Incorporation into a High-oxidation-state Manganese Aggregate, and Reversible Redox Processes for the [Mn4O3X(OAc)3(dbm)3] (X=Cl, Br) Complexes. J. Chem. Soc., Chem. Commun.1992, 1427-1429.
    90289
  49. Chacon, S.T.; Chisholm, M.H.; Cook, C.M.; Hampden-Smith, M.J.; Streib, W.E.: New Routes to Alkylidyne-Bridged Ditungsten Compounds Supported by Alkoxide or Siloxide Ligands by the Activation of Ethylene. Angew. Chem. 1992, 104, 467-469. Angew. Chem. Int. Ed. Engl. 1992, 31, 462-464. 91270,
    89081
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